Synthesis of double perovskite La2MnNiO6 nanoparticles as highly efficient oxygen evolution electro-catalysts

Double perovskite La₂MnNiO₆ nanoparticles (approximately 30 nm in diameter) were synthesized using a modified sol-gel method followed by a firing process and used as promising electrode materials for oxygen evolution reactions (OERs). The phase purity of the nanoparticles was verified using X-ray diffraction and Raman spectroscopy measurements. La₂MnNiO₆ nanoparticles crystallize in a monoclinic structure (P2₁/n space group) with refined lattice parameters of a = 5.461(5) Å, b = 5.512(3) Å, c = 7.760(5) Å, and β = 90.10(2)°. The elemental composition, particle size, size distribution, and surface area of the La₂MnNiO₆ nanoparticles were also investigated. La₂MnNiO₆ nanoparticles are ferromagnetic in nature and exhibit hysteresis with a saturation magnetization value of approximately 9 emu/g. La₂MnNiO₆ nanoparticles exhibit highly efficient electro-catalytic activity for OERs with a low onset over-potential (approximately 65 mV) and low Tafel slope values (120 mV/dec) in alkaline media. The over-potential of La₂MnNiO₆ nanoparticles at a current density of 10 mA/cm² is in good agreement with the reported over-potential (ƞ₁₀) of double perovskites, commercial Pt/C and IrO₂ electro-catalysts for promoting OERs.     

FeOOH–CoS composite catalyst with high catalytic performances for oxygen evolution reaction at high current density

Water electrolysis is an efficient approach for high-purity hydrogen production. However, the anodic sluggish oxygen evolution reaction (OER) always needs high overpotential and thus brings about superfluous electricity cost of water electrolysis. Therefore, exploiting highly efficient OER electrocatalysts with small overpotential especially at high current density will undoubtedly boost the development of industrial water electrolysis. Herein, we used a simple hydrothermal method to prepare a novel FeOOH–CoS nanocomposite on nickel foam (NF). The as-prepared FeOOH–CoS/NF catalyst displays an excellent OER performance with extremely low overpotentials of 306 and 329 mV at 500 and 1000 mA cm⁻² in 1.0 M KOH, respectively. In addition, the FeOOH–CoS/NF catalyst can maintain excellent catalytic stability for more than 50 h, and the OER catalytic activity shows almost no attenuation no matter after 1000 repeated CV cycles or 50 h of stability test. The high catalytic activity and stability have exceeded most non-noble metal electrocatalysts reported in literature, which makes the FeOOH–CoS/NF composite catalyst have promising applications in the industrial water electrolysis.     

东营凹陷纯化潜山构造特征与勘探目标选择

结合钻井和地震资料研究纯化潜山的构造特征，精细描述了纯化潜山的构造演化过程，在此基础上探讨了纯化潜山的烃源岩、储集层、盖层以及圈闭等油气成藏条件，研究表明，纯化潜山属于典型的块断山，其形成演化与石村断层的发育及潜山北部利津洼陷的强烈下陷有着密切关系。纯化潜山储、盖条件以及圈闭条件都较好，油气成藏的主控因素是烃源岩以及油气运移通道，纯化潜山南部沿石村断层上盘一线为较有利的勘探目标区。     

骆马湖生态建设

骆马湖为浅水湖泊,具有典型的过水性特征,已经处于中富营养化阶段。通过对骆马湖富营养化发生机制的研究,发现入湖河道携入大量营养物质入湖和水生植物的破坏是骆马湖富营养化进程加快的主要原因。为了保护骆马湖水质,提出对骆马湖生态建设的意见:建立自然保护区,建设入湖口人工湿地,建设骆马湖生态湖滨,通过生态渔业和生态旅游实现骆马湖的可持续开发。     

流域生态环境需水计算

介绍了我国流域生态需水研究现状,在对流域生态环境需水计算的前提条件进行阐述的基础上,根据生态需水的水文学原理以及生态系统学原理,从8个方面提出了流域生态环境需水的计算方法,以确定整个流域的生态环境需水量,从而合理量化生态需水总量,达到水资源优化配置的目的.     

基于进化算法的常减压装置模拟

提出了基于优选优生进化算法（Select—best and prepotency evolution algorithm，SPEA）的常减压装置模拟方法。以各塔的温度分布为目标，基于生产过程和分析数据，采用SPEA确定各塔板Murphree效率，从而精确描述各塔板平衡偏离程度。在实际应用中，获得具有良好精度的常减压装置模型。系统分析了SPEA算法的关键参数——优选领域大小与计算复杂性及寻优性能之间的关系，结果显示其取值为群体规模的10％最为合适。     

上海市水环境生态安全评价

从“状态—压力—响应”指标框架体系出发,针对上海市水环境生态系统的现状特点,从时间变化和空间对比分析角度分别建立了上海市水环境生态安全评价指标体系;利用标准化和变异系数法确定各指标的标准化值和权重,采用综合指数评价法得到安全评价的综合指数值。在此基础上采用等级划分法,建立起综合指数值与生态安全评判的等级关系。各指标层的变化趋势揭示了上海市水环境生态安全的现状和发展趋势,即中心城区的水环境生态安全等级普遍低于郊区;在年际变化上,状态指标层评价值呈下降趋势,需要持续保护水环境生态系统;而压力和响应指标层评价值不断上升,保证了总体的良性发展趋势。     

H.264/AVC技术进展及其务实发展策略思考

结合NGN及3G演进的固定、移动视频业务实际需求状况，论述H．264／AVC的重要技术进展及其务实发展策略。     

Antenna-array pattern nulling using a differential evolution algorithm

A new method based on the differential evolution (DE) algorithm is proposed for antenna-array pattern synthesis with prescribed nulls. The array excitation amplitudes are the only controlling parameters, and the objectives are to synthesize array patterns with nulls imposed on directions of interferences while keeping the sidelobe levels (SLLs) below prescribed levels. Many factors such as the excitation dynamic range ratio, null depth level, null width, and SLLs are taken into account in the synthesis. Simulation results of several typical problems are compared with published results to illustrate the effectiveness of the proposed method. © 2003 Wiley Periodicals, Inc. Int J RF and Microwave CAE 14: 57–63, 2004.     

水量还原方法及合理性检查

文中详细地阐述了取河水、井水、水库水、跨流城引(排)水等不同情况进行还原的具体方法步骤。并对水量还原成果提出合理性检查措施。